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Evidence for the widespread occurrence of short- and medium-chain chlorinated paraffins in fish collected from the Rhône River basin (France)
| Content Provider | Hyper Articles en Ligne (HAL) |
|---|---|
| Author | Labadie, Pierre Blasi, Charlotte Menach, Karyn Le Geneste, Emmanuel Babut, Marc Perceval, Olivier Budzinski, Hélène |
| Abstract | Chlorinated paraffins (CPs) are high-volume chemicals used in numerous industrial applications. Their quantitative analysis is extremely challenging and this work presents the optimization of an analytical method based on gas chromatography hyphenated with electron capture negative ionization time-of-flight high-resolution mass spectrometry (GC-ECNI-TOF HRMS) for the simultaneous determination of short-chain and medium-chain CPs (SCCPs and MCCPs, respectively) in fish tissues (i.e. dorsal muscle). The resolution of the TOF-MS analyzer reduced or eliminated isobaric interferences and the CP response was optimized through Design of Experiment. A simple clean-up |
| Ending Page | 239 |
| Page Count | 8 |
| Starting Page | 232 |
| File Format | |
| ISSN | 00456535 |
| DOI | 10.1016/j.chemosphere.2019.02.069 |
| Journal | Chemosphere |
| Volume Number | 223 |
| Language | English French |
| Publisher | Elsevier |
| Publisher Date | 2019-05-01 |
| Access Restriction | Open |
| Subject Keyword | sde Environmental Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Public Health, Environmental and Occupational Health Environmental Engineering |
