NDLI: Synthesis, Crystal Structure, Hydrogen Bonding and Thermal Behaviour of a Three-Dimensional Cu(II)-benzene-1,2,4,5-tetracarboxylate Templated by 1,9-Diaminononane

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Synthesis, Crystal Structure, Hydrogen Bonding and Thermal Behaviour of a Three-Dimensional Cu(II)-benzene-1,2,4,5-tetracarboxylate Templated by 1,9-Diaminononane

Content Provider	Hyper Articles en Ligne (HAL)
Author	Köferstein, Roberto Robl, Christian
Abstract	Triclinic single crystals of Cu 4 (H 3 N-(CH 2) 9-NH 3)(OH) 2 [C 6 H 2 (COO) 4 ] 2 ·5H 2 O were prepared in aqueous solution at 80 °C in the presence of 1,9-diaminononane. Space group P (no. 2) with a = 1057.5(2), b = 1166.0(2), c = 1576.7(2) pm, α = 106.080(10)°, = 90.73(2)° and = 94.050(10)°. The four crystallographic independent Cu 2+ ions are surrounded by five oxygen atoms each with Cu-O distances between 191.4(3) and 231.7(4) pm. The connection between the Cu 2+ coordination polyhedra and the [C 6 H 2 (COO) 4 ] 4-anions yields three-dimensional framework with negative excess charge and wide centrosymmetric channel-like voids. These voids extend parallel to [001] with the diagonal of the nearly rectangular cross-section of approximately 900 pm. The channels of the framework accommodate [H 3 N-(CH 2) 9-NH 3 ] 2+ cations and water molecules, which are not connected to Cu 2+. The nonane-1,9-diammonium cations adopt a partial gauche conformation. Thermoanalytical measurements in air show a loss of water of crystallization starting at 90 °C and finishing at approx. 170 °C. The dehydrated compound is stable up to 260 °C followed by an exothermic decomposition yielding copper oxide.
Ending Page	1942
Page Count	6
Starting Page	1937
File Format	PDF
ISSN	00442313
e-ISSN	15213749
DOI	10.1002/zaac.201400177
Journal	Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie
Issue Number	10
Volume Number	640
Language	English
Publisher	Wiley-VCH Verlag
Publisher Date	2014-06-05
Access Restriction	Open
Subject Keyword	Coordination compounds Metal organic frameworks MOFs benzene carboxylate Copper compounds Copper Complexes chim Chemical Sciences Coordination chemistry Cristallography Inorganic chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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