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Access to (Hetero) arylated Selenophenes via Palladium-catalysed Stille, Negishi or Suzuki Couplings or C-H Bond Functionalization Reaction
| Content Provider | Hyper Articles en Ligne (HAL) |
|---|---|
| Author | Skhiri, Aymen Salem, Ridha Ben Soulé, Jean-François Doucet, Henri |
| Abstract | (Hetero) aryl-substituted selenophenes exhibit important physical properties especially for optoelectronics. Palladium-catalysed coupling reactions currently represent the most efficient methods to prepare such (hetero) arylated selenophene derivatives. Initially, Stille coupling was the most efficient reaction for the synthesis of these compounds; however, over the last decade, Suzuki coupling has become the most commonly employed. Recently, Pd-catalysed arylation via the C-H bond activation of selenophenes has proved to be a very convenient alternative method for the preparation of several arylated selenophenes as there is no need to prepare organometallic derivatives. In this Review, the progress and substrate scope in the synthesis of both C2-and C3-arylated selenophenes via Pd-catalysis are summarized. |
| Ending Page | 2913 |
| Page Count | 19 |
| Starting Page | 2895 |
| File Format | |
| ISSN | 18673899 |
| DOI | 10.1002/cctc.201700256 |
| Journal | ChemCatChem |
| Issue Number | 15 |
| Volume Number | 9 |
| Language | English |
| Publisher | Wiley |
| Publisher Date | 2017-01-01 |
| Access Restriction | Open |
| Subject Keyword | selenophenes coupling c-h activation arylated palladium chim Chemical Sciences Catalysis |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Physical and Theoretical Chemistry Catalysis Inorganic Chemistry |
