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Hydrate equilibrium data for the CO2+N2 system with the use of Tetra-nbutylammonium bromide (TBAB), cyclopentane (CP) and their mixture
| Content Provider | Hyper Articles en Ligne (HAL) |
|---|---|
| Author | Fragkiskos, Tzirakis Stringari, Paolo Solms, Nicolas Von Coquelet, Christophe Kontogeorgis, Georgios M. |
| Abstract | Carbon Dioxide capture and sequestration (CCS) is nowadays an important area of research for decreasing CO2 emissions worldwide. Hydrates can become of great importance in the future as they form the basis for a new technology that can be used for CO2 capture from flue gases (hydrate crystallization). In this work hydrate equilibrium data are measured and compared with literature data. In particular, experimental results for hydrate dissociation with several promoters are presented. The isochoric method is used to determine the gas hydrate dissociation points. Different CO2 þ N2 gas mixtures were used with presence of promoters such as tetra-n-butylammonium bromide (TBAB), cyclopentane (CP) and mixtures of TBAB with CP. The novelty of this work is the combination of promoters, TBAB and CP, which under certain conditions induced greater pressure reduction in comparison to pure TBAB results. Concerning experiments with pure promoters, there is excellent consistency between our results and literature results for different gas mixtures and promoter concentrations. Finally, experimental uncertainties for temperature, pressure, and molar composition are also presented. |
| File Format | |
| ISSN | 03783812 |
| DOI | 10.1016/j.fluid.2015.09.021 |
| Journal | Fluid Phase Equilibria |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2015-09-09 |
| Access Restriction | Open |
| Subject Keyword | TBAB CP Promotion Carbon dioxide spi Engineering Sciences [physics] Chemical and Process Engineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy Physical and Theoretical Chemistry Chemical Engineering |