NDLI: Supramolecular Crystal Networks Constructed from Cucurbit[8]uril with Two Naphthyl Groups.

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Supramolecular Crystal Networks Constructed from Cucurbit[8]uril with Two Naphthyl Groups.

Content Provider	Europe PMC
Author	Gao, Zhong-Zheng Shen, Lei Hu, Yu-Lu Sun, Ji-Fu Wei, Gang Zhao, Hui
Editor	Zhang, Afang
Copyright Year	2022
Abstract	Naphthyl groups are widely used as building blocks for the self-assembly of supramolecular crystal networks. Host-guest complexation of cucurbit[8]uril (Q[8]) with two guests NapA and Nap1 in both aqueous solution and solid state has been fully investigated. Experimental data indicated that double guests resided within the cavity of Q[8], generating highly stable homoternary complexes NapA₂@Q[8] and Nap1₂@Q[8]. Meanwhile, the strong hydrogen-bonding and π···π interaction play critical roles in the formation of 1D supramolecular chain, as well as 2D and 3D networks in solid state.
Journal	Molecules
Volume Number	28
DOI	10.3390/molecules28010063
PubMed Central reference number	PMC9822147
Issue Number	1
PubMed reference number	36615258
e-ISSN	14203049
Language	English
Publisher	Molecular Diversity Preservation International (MDPI)
Publisher Date	2022-12-21
Access Restriction	Open
Subject Keyword	cucurbit[8]uril naphthyl group host–guest chemistry self-assembly supramolecular network
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Medicine Chemistry Drug Discovery Pharmaceutical Science Analytical Chemistry Molecular Medicine Organic Chemistry

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