NDLI: Microporous Polymelamine Framework Functionalized with Re(I) Tricarbonyl Complexes for CO<sub>2</sub> Absorption and Reduction.

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Microporous Polymelamine Framework Functionalized with Re(I) Tricarbonyl Complexes for CO₂ Absorption and Reduction.

Content Provider	Europe PMC
Author	Zappia, Stefania Perju, Elena Bejan, Andrei Coroaba, Adina Bossola, Filippo Zeng, Juqin Sassone, Daniele Marin, Luminita Destri, Silvia Porzio, William
Editor	Yang, Chen-I
Copyright Year	2022
Abstract	A mixture of polymeric complexes based on the reaction between Re(CO)5Cl and the porous polymeric network coming from the coupling of melamine and benzene-1,3,5-tricarboxaldehyde was obtained and characterized by FTIR, NMR, SEM, XPS, ICP, XRD, and cyclic voltammetry (CV). The formed rhenium-based porous hybrid material reveals a noticeable capability of CO2 absorption. The gas absorption amount measured at 295 K was close to 44 cm3/g at 1 atm. An interesting catalytic activity for CO2 reduction reaction (CO2RR) is observed, resulting in a turn over-number (TON) close to 6.3 under 80 min of test at −1.8 V vs. Ag/AgCl in a TBAPF6 0.1 M ACN solution. A possible use as filler in membranes or columns can be envisaged.
Journal	Polymers
Volume Number	14
PubMed Central reference number	PMC9782493
Issue Number	24
PubMed reference number	36559839
e-ISSN	20734360
DOI	10.3390/polym14245472
Language	English
Publisher	MDPI
Publisher Date	2022-12-14
Access Restriction	Open
Rights License	Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). © 2022 by the authors.
Subject Keyword	porous organic polymers melamine-based polymers rhenium CO2 absorption CO2 electrochemical reduction
Content Type	Text
Resource Type	Article
Subject	Chemistry Polymers and Plastics

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