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Competing Routes in the Extraction of Lanthanide Nitrates by 1,10-Phenanthroline-2,9-diamides: An Impact of Structure of Complexes on the Extraction.
| Content Provider | Europe PMC |
|---|---|
| Author | Ustynyuk, Yuri A. Zhokhova, Nelly I. Gloriozov, Igor P. Matveev, Petr I. Evsiunina, Mariia V. Lemport, Pavel S. Pozdeev, Anton S. Petrov, Vladimir G. Yatsenko, Alexandr V. Tafeenko, Viktor A. Nenajdenko, Valentine G. |
| Editor | Akitsu, Takashiro |
| Copyright Year | 2022 |
| Abstract | The fact of the fracture of the extraction curve of lanthanides by 1,10-phenanthroline-2,9-diamides is explained in terms of the structure of complexes, solvent extraction data and quantum chemical calculations. The solvent extraction proceeds in two competing directions: in the form of neutral complexes LLn(NO3)3 and in the form of tight ion pairs {[LLn(NO3)2 H2O]+ (NO3-). |
| Journal | International Journal of Molecular Sciences [Int J Mol Sci] |
| Volume Number | 23 |
| DOI | 10.3390/ijms232415538 |
| PubMed Central reference number | PMC9779341 |
| Issue Number | 24 |
| PubMed reference number | 36555179 |
| e-ISSN | 14220067 |
| Language | English |
| Publisher | Molecular Diversity Preservation International (MDPI) |
| Publisher Date | 2022-12-08 |
| Access Restriction | Open |
| Subject Keyword | lanthanides N,O-hybrid ligands complex DFT calculations X-ray diffraction |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Molecular Biology Spectroscopy Catalysis Computer Science Applications Medicine Inorganic Chemistry Organic Chemistry |
