NDLI: Phenyloxycarbonyl (Phoc) Carbamate: Chemioselective Reactivity and Tetra-<i>n</i>-butylammonium Fluoride Deprotection Study.

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Phenyloxycarbonyl (Phoc) Carbamate: Chemioselective Reactivity and Tetra-n-butylammonium Fluoride Deprotection Study.

Content Provider	Europe PMC
Author	Huguenot, Florent Vidal, Michel
Copyright Year	2022
Abstract	We present the resultsof the chemoselective reactivity of phenylcarbamates.Phenylcarbamates of primary amines are reactive to form urea, andphenylcarbamates of secondary amines can be used as tags due to theexistence of rotamers. Moreover, deprotection attempts to to recoverthe primary amines in use of a catalytic amount of TBAF show the possibilityof obtaining the symmetrical urea from the corresponding phenylcarbamate.We have begun the study of the transformation of Phoc carbamates intothe corresponding free amines by TBAF. We present here our most significantresults concerning the sensitivity of this reaction in terms of thesolvent and substrate.
Journal	ACS Omega
Volume Number	7
PubMed Central reference number	PMC9753175
Issue Number	49
PubMed reference number	36530256
e-ISSN	24701343
DOI	10.1021/acsomega.2c04979
Language	English
Publisher	American Chemical Society
Publisher Date	2022-11-28
Access Restriction	Open
Rights License	Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). © 2022 The Authors. Published by American Chemical Society
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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