NDLI: Photocatalytic Aerobic Oxidation of Biomass-Derived 5-HMF to DFF over MIL-53(Fe)/g-C<sub>3</sub>N<sub>4</sub> Composite.

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Photocatalytic Aerobic Oxidation of Biomass-Derived 5-HMF to DFF over MIL-53(Fe)/g-C₃N₄ Composite.

Content Provider	Europe PMC
Author	Huang, Danyao Wang, Hao Wu, Ying
Editor	Tahir, Muhammad
Copyright Year	2022
Abstract	A MIL-53(Fe)/g-C₃N₄ heterogeneous composite was synthesized and applied in photocatalytic oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). The systematic investigation indicated that the introduction of MIL-53(Fe) into g-C₃N₄ increased the specific surface area, broadened the visible-light response region, and promoted the separation efficiency of the photo-generated electron-hole pairs. The 10% MIL-53(Fe)/g-C₃N₄ heterogeneous composite achieved the best photocatalytic oxidation activity with 74.5% of 5-HMF conversion under simulated sunlight, which was much higher than that of pristine g-C₃N₄ and MIL-53(Fe). The MIL-53(Fe)/g-C₃N₄ composite displayed good photocatalytic reusability and stability. Based on the characterization results and photocatalytic performance, a Z-scheme photocatalytic mechanism of the MIL-53(Fe)/g-C₃N₄ composite was suggested, and a possible reaction route was deduced.
Journal	Molecules
Volume Number	27
DOI	10.3390/molecules27238537
PubMed Central reference number	PMC9740462
Issue Number	23
PubMed reference number	36500631
e-ISSN	14203049
Language	English
Publisher	Molecular Diversity Preservation International (MDPI)
Publisher Date	2022-12-04
Access Restriction	Open
Subject Keyword	photocatalysis aerobic oxidation MIL-53(Fe)/g-C3N4 heterojunction composite
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Medicine Chemistry Drug Discovery Pharmaceutical Science Analytical Chemistry Molecular Medicine Organic Chemistry

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Photocatalytic Aerobic Oxidation of Biomass-Derived 5-HMF to DFF over MIL-53(Fe)/g-C3N4 Composite.

Photocatalytic Aerobic Oxidation of Biomass-Derived 5-HMF to DFF over MIL-53(Fe)/g-C₃N₄ Composite.