NDLI: Binding of permanganate anion to pentaammineazidocobalt(III) cation in solution and solid phases: synthesis, characterization, X-ray structure, and genotoxic effects of [Co(NH3)5N3](MnO4)2⋅H2O.

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Binding of permanganate anion to pentaammineazidocobalt(III) cation in solution and solid phases: synthesis, characterization, X-ray structure, and genotoxic effects of [Co(NH₃)₅N₃](MnO₄)₂⋅H₂O.

Content Provider	Europe PMC
Author	BALA, Ritu KIM, Jinkwon PRAKASH, Vinit
Copyright Year	2021
Abstract	A pentaammineazidocobalt(III) complex, [Co(NH3)5N3](MnO4)2XH2O has been synthesized by an one-pot synthesis method. It was characterized by studies such as infrared (IR) and UV-visible spectroscopy. The single crystal X-ray structure analysis revealed that the title complex crystallizes in space group Cc. The cobalt center is six coordinated with slightly octahedral geometry. The supramolecular architecture is also formed by intermolecular N-H…O (anion and H2O) and Mn-O…O-H hydrogen bonds. The binding property of the cation, [Co(NH3)5N3]2+ with the anion, MnO4– has also been determined (in solution phase) with the help of UV-visible spectroscopic titrations. Further, the genotoxic effects of KMnO4, [Co(NH3)5N3]Cl2 and [Co(NH3)5N3](MnO4)2XH2O were studied usingAllium cepa root chromosomal aberration assay and it revealed that the genotoxicity of the newly synthesized complex is 1.97–1.76 fold, which is less compared to KMnO4. The order of genotoxic potential has been observed to be KMnO4 > [Co(NH3)5N3](MnO4)2XH2O > [Co(NH3)5N3]Cl2.
Related Links	https://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC8517615&blobtype=pdf
ISSN	13000527
Journal	Turkish Journal of Chemistry [Turk J Chem]
Volume Number	45
DOI	10.3906/kim-2012-66
PubMed Central reference number	PMC8517615
Issue Number	4
PubMed reference number	34707431
e-ISSN	13036130
Language	English
Publisher	The Scientific and Technological Research Council of Turkey
Publisher Date	2021-08-27
Access Restriction	Open
Rights License	This article is distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/ ), which permits unrestricted use and redistribution provided that the original author and source are credited. Copyright © 2021 The Author(s)
Subject Keyword	Anion binder pentaammineazidocobalt(III) coordination chemistry genotoxicity IR spectroscopy X-ray crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry

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