NDLI: Syntheses and crystal structures of [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}ClH]Cl·2.75CH2Cl2 and its derivatives, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}(CH2CO2Et)Cl]Cl·CH3OH·0.5H2O, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}Cl2]Cl·CH3OH·2H2O and [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}(CH2CO2Et)(CO)]Cl2·2CH2Cl2·1.5H2O.

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Syntheses and crystal structures of [Ir^III{C(CHCO₂Et)(dppm)₂-κ⁴ P,C,C',P'}ClH]Cl·2.75CH₂Cl₂ and its derivatives, [Ir^III{C(CHCO₂Et)(dppm)₂-κ⁴ P,C,C',P'}(CH₂CO₂Et)Cl]Cl·CH₃OH·0.5H₂O, [Ir^III{C(CHCO₂Et)(dppm)₂-κ⁴ P,C,C',P'}Cl₂]Cl·CH₃OH·2H₂O and [Ir^III{C(CHCO₂Et)(dppm)₂-κ⁴ P,C,C',P'}(CH₂CO₂Et)(CO)]Cl₂·2CH₂Cl₂·1.5H₂O.

Content Provider	Europe PMC
Author	Schlapp-Hackl, Inge Falschlunger, Christoph Zauner, Kathrin Schuh, Walter Kopacka, Holger Wurst, Klaus Peringer, Paul
Copyright Year	2019
Page Count	9
Volume Number	75
PubMed Central reference number	PMC6323871
Issue Number	Pt 1
Issue Number	pt 1
PubMed reference number	30713725
Journal	Acta Crystallographica Section E: Crystallographic Communications [Acta Crystallogr E Crystallogr Commun]
e-ISSN	20569890
DOI	10.1107/S2056989018017024
Language	English
Publisher	International Union of Crystallography
Publisher Date	2019-01-01
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricteduse, distribution, and reproduction in any medium, provided the original authors and source are cited. © Schlapp-Hackl et al. 2019
Subject Keyword	carbodiphosphorane (CDP) PCP pincer diazo compounds cycloaddition iridium(III) C–C coupling reaction non-innocent behaviour alkylidene bridge carbene intermediate insertion reaction crystal structure
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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