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Crystal structure of bis-{N-[2-(di-methyl-amino)-eth-yl]quinolin-8-amine-κ(3) N,N',N''}nickel(II) dichloride 3.5-hydrate.
| Content Provider | Europe PMC |
|---|---|
| Author | Kariuki, Benson M. Al-Sudani, Abdul-Razak H. |
| Copyright Year | 2014 |
| Abstract | In the title compound, [Ni(C13H17N3)2]Cl2·3.5H2O, the geometry of the NiN6 complex cation is slightly distorted octahedral, with a facial arrangement of the two tridentate N-[2-(dimethylamino)ethyl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-molecules located on centres of inversion, together with two chloride counter-anions and 3.5 water molecules of solvation, one of which is disordered across an inversion centre. In the crystal, O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding interactions form a three-dimensional network structure. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 70 |
| PubMed Central reference number | PMC4186116 |
| Issue Number | Pt 9 |
| Issue Number | pt 9 |
| PubMed reference number | 25309190 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536814019035 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2014-08-30 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permitsunrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Kariuki and Al-Sudani 2014 |
| Subject Keyword | crystal structure N-[2-(dimethylamino)ethyl]quinolin-8-amine nickel(II) complex hydrogen bonding |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
