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catena-Poly[2-methyl-pyridinium [tungstate-di-μ-selenido-silver-di-μ-selenido] 2-methyl-pyridine monosolvate].
| Content Provider | Europe PMC |
|---|---|
| Author | Zhou, Lu-Jun Shi, Hua-Tian Xu, Chao Chen, Qun Zhang, Qian-Feng |
| Copyright Year | 2013 |
| Abstract | The title compound, {(C6H8N)[AgWSe4]·C6H7N}n, consists of anionic [WAgSe4]n chains, 2-methylpyridinium cations and neutral 2-methylpyridine molecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms are located on a twofold rotation axis and each metal atom is coordinated by four Se atoms in distorted tetrahedral geometry. In the crystal, the 2-methylpyridinium cation and 2-methylpyridine molecule are linked via N—H⋯N hydrogen bonding. Weak C—H⋯Se interactions link the organic components and polymeric anions into a three-dimensional architecture. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 69 |
| PubMed Central reference number | PMC3884262 |
| Issue Number | Pt 11 |
| Issue Number | pt 11 |
| PubMed reference number | 24454038 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536813028213 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2013-10-19 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Zhou et al. 2013 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |