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Metal ion-directed solution-phase tailoring: from large-area graphene oxide into nanoscale pieces.
| Content Provider | Europe PMC |
|---|---|
| Author | Wang, Xiansong Huang, Peng Liu, Huiyang Li, Chao Shen, Guangxia Cui, Daxiang |
| Copyright Year | 2013 |
| Abstract | Due to fascinating electronic properties and great potential in various applications, graphene has attracted great interest. Recently, much work have focused on the synthesis of different sizes and properties of graphene or graphene oxides (GOs), for example, graphene nanoribbons, nanosized graphene pieces, and nanosized triangular and hexagonal graphene sheets terminated by zigzag edges. Herein, we have demonstrated a widely available approach to fabricate the nanoscale GO pieces by directly solution-phase cutting a large-area GO sheet into nanoscale pieces via spontaneous redox reactions at room temperature. In this process, GO acts with dual functions as a model and a reducing reagent. With a typical example of silver ions, we have investigated in detail the influence of the reaction time and concentration of metal ions on yield and size of nanoscale GO pieces. Moreover, we also obtain Ag nanoparticle coating on the GO surface. Finally, a possible mechanism is suggested to explain the formation of nanoscale GO pieces. |
| ISSN | 19317573 |
| Journal | Nanoscale Research Letters |
| Volume Number | 8 |
| PubMed Central reference number | PMC3665674 |
| Issue Number | 1 |
| PubMed reference number | 23672471 |
| e-ISSN | 1556276X |
| DOI | 10.1186/1556-276x-8-226 |
| Language | English |
| Publisher | Springer |
| Publisher Date | 2013-05-14 |
| Access Restriction | Open |
| Rights License | This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Copyright ©2013 Wang et al.; licensee Springer. |
| Subject Keyword | Graphene oxides Nanoscale graphene oxide pieces Spontaneous redox reaction Metal particles |
| Content Type | Text |
| Resource Type | Article |
| Subject | Nanoscience and Nanotechnology Condensed Matter Physics Materials Science |