NDLI: Redetermination of cis-bis-(ethyl-ene-diamine-κ(2) N,N')bis-(nitrito-κN)cobalt(III) (ethyl-enediamine-κ(2) N,N')tetra-kis-(nitrito-κN)cobaltate(III) monohydrate.

Please wait, while we are loading the content...

Redetermination of cis-bis-(ethyl-ene-diamine-κ(2) N,N')bis-(nitrito-κN)cobalt(III) (ethyl-enediamine-κ(2) N,N')tetra-kis-(nitrito-κN)cobaltate(III) monohydrate.

Content Provider	Europe PMC
Author	Burrow, Robert A. Vicenti, Juliano R. de Menezes
Copyright Year	2013
Abstract	The structure of the title compound, [Co(NO2)2(NH2CH2CH2NH2)2][Co(NO2)4(NH2CH2CH2NH2)]·H2O, was redetermined with a modern CCD-equipped diffractometer. In comparison with the original determination based on photographic data [Kushi et al. (1976 ▶). Inorg. Nucl. Chem. Lett. 12, 629–633], the current study allows the location of reliable postions for the H atoms and thus leads to better understanding of the interionic and intermolecular interactions. The crystal structure consists of an octahedrally coordinated cationic CoIII complex ion, an octahedrally coordinated anionic CoIII complex ion and a lattice water molecule. The complex cation, complex anion and lattice water molecule are connected by an intricate network of O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional structure.
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	69
PubMed Central reference number	PMC3588370
Issue Number	Pt 1
Issue Number	pt 1
PubMed reference number	23476350
e-ISSN	16005368
DOI	10.1107/s1600536812050325
Language	English
Publisher	International Union of Crystallography
Publisher Date	2012-12-15
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Burrow and Vicenti 2013
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in