NDLI: Bis(2,2':6',2''-terpyridine)-ruthenium(II) bis-(perchlorate) hemihydrate.

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Bis(2,2':6',2''-terpyridine)-ruthenium(II) bis-(perchlorate) hemihydrate.

Content Provider	Europe PMC
Author	Kozlowska, Mariana Rodziewicz, Pawel Brus, Diana Malgorzata Breczko, Joanna Brzezinski, Krzysztof
Copyright Year	2012
Abstract	The asymmetric unit of the title compound, [Ru(C15H11N3)2](ClO4)2·0.5H2O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-molecule of water. Face-to-face and face-to-edge π-stacking interactions between terpyridine units [centroid–centroid distances = 3.793 (2) and 3.801 (2) Å] stabilize the crystal lattice The partially occupied water molecule interacts with two perchlorate ions via O—H⋯O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction.
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	68
PubMed Central reference number	PMC3515152
Issue Number	Pt 11
Issue Number	pt 11
PubMed reference number	23284379
e-ISSN	16005368
DOI	10.1107/s1600536812043917
Language	English
Publisher	International Union of Crystallography
Publisher Date	2012-10-27
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Kozlowska et al. 2012
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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