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(E)-N'-(4-Meth-oxy-benzyl-idene)-2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetohydrazide.
| Content Provider | Europe PMC |
|---|---|
| Author | Fun, Hoong-Kun Chia, Tze Shyang Frank, Priya V. Poojary, Mahesha Kalluraya, Balakrishna |
| Copyright Year | 2012 |
| Abstract | In the title compound, C14H15N5O4, the central –C=N—N—C(=O)—C– bridge is nearly planar [maximum deviation = 0.037 (1) Å] and forms dihedral angles of 7.37 (9) and 73.33 (5)°, respectively, with the benzene and imidazole rings. The dihedral angle between the benzene and imidazole rings is 66.08 (9)°. The methoxy and nitro groups are nearly coplanar with the benzene and imidazole rings, respectively, with a C—O—C—C torsion angle of 5.9 (2)° and an O—N—C—C angle of −0.2 (2)°. In the crystal, molecules are linked by a pair of N—H⋯O hydrogen bonds with an R 2 2(8) ring motif, forming an inversion dimer. The dimers are further interconnected by C—H⋯O hydrogen bonds into a sheet parallel to the (111) plane. A C—H⋯π interaction is also observed between the sheets. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 68 |
| PubMed Central reference number | PMC3470350 |
| Issue Number | Pt 10 |
| Issue Number | pt 10 |
| PubMed reference number | 23125763 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536812039621 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2012-09-22 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Fun et al. 2012 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
