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3-Amino-benzoic acid-4,4'-bipyridine (2/3).
| Content Provider | Europe PMC |
|---|---|
| Author | Lhengwan, Pornsuda Achiwawanich, Supakit Duangthongyou, Tanwawan |
| Copyright Year | 2012 |
| Abstract | The asymmetric unit of the title compound, 3C10H8N2·2C7H7NO2, consists of three molecules of 4,4′-bipyridine (bpy) and two molecules of 3-aminobenzoic acid (bza). Two molecules of bza and two molecules of bpy are connected via O—H⋯N, N—H⋯N and N—H⋯O hydrogen bonds, forming forming infinite double-stranded zigzag chains along the c axis. The third molecule of bpy is linked to the chain by weak C—H⋯O interactions. Adjacent chains are linked via π–π interactions [centroid–centroid distances = 3.759 (3)–3.928 (3) Å] involving the pyridine rings of bpy molecules, resulting in a sheet-like structure parallel to (100). These sheets are stacked via C—H⋯π interactions, resulting finally in the formation of a three-dimensional supramolecular structure. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 68 |
| PubMed Central reference number | PMC3415010 |
| Issue Number | Pt 8 |
| Issue Number | pt 8 |
| PubMed reference number | 22904997 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536812033181 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2012-07-28 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Lhengwan et al. 2012 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |