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Aqua-trichlorido(1-cyano-methyl-4-aza-1-azoniabicyclo-[2.2.2]octane-κN(4))copper(II) monohydrate.
| Content Provider | Europe PMC |
|---|---|
| Author | Zhou, Qinqin Zhang, Yi |
| Copyright Year | 2012 |
| Abstract | The asymmetric unit of the title compound, [CuCl3(C8H14N3)(H2O)]·H2O, comprises a neutral complex and a molecule of free water. The complex contains coordinated CuII ions, with Cu—Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu—N and Cu—O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonds link the molecules into a three-dimensional structure. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 68 |
| PubMed Central reference number | PMC3344395 |
| Issue Number | Pt 5 |
| Issue Number | pt 5 |
| PubMed reference number | 22590157 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536812017205 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2012-04-25 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Zhou and Zhang 2012 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |