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Poly[di-μ(3)-chlorido-di-μ(2)-chlorido-{μ(4)-N,N,N',N'-tetra-kis-[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine-κ(4)P:P':P'':P'''}tetra-copper(II)].
| Content Provider | Europe PMC |
|---|---|
| Author | Liu, Jia-Qin Zhang, Yan Lü, Ya-Jing Jiang, Zhen-Jü |
| Copyright Year | 2012 |
| Abstract | In the title complex, [Cu4Cl4(C58H52N2P4)]n, four CuII atoms are held together via two doubly bridging and two triply bridging chlorides, forming a stair-like Cu4Cl4 core having crystallographically imposed inversion symmetry, while the benzene-1,4-diamine ligand (with a crystallographic inversion center at the centroid) acts in a tetradentate coordination mode, bridging two adjacent Cu4Cl4 cores, resulting in a chain along the a-axis direction. One Cu atom has a distorted tetrahedral geometry, coordinated by one P atom, one μ2-Cl and two μ3-Cl atoms, while the second Cu atom adopts a trigonal geometry, coordinated by one P atom, one μ2-Cl and one μ3-Cl atoms. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 68 |
| PubMed Central reference number | PMC3343832 |
| Issue Number | Pt 4 |
| Issue Number | pt 4 |
| PubMed reference number | 22589806 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536812010860 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2012-03-17 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Liu et al. 2012 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
