[2-Butyl-4-(4-tert-butyl-benz-yl)-1,2,4-triazol-3-yl-idene]chlorido[(1,2,5,6-η)-cyclo-octa-1,5-diene]iridium(I).

Content Provider	Europe PMC
Author	Nichol, Gary S. Walton, David P. Anna, Laura J. Rajaseelan, Edward
Copyright Year	2012
Abstract	In the title compound, [IrCl(C8H12)(C17H25N3)], the IrI ion has a distorted square-planar coordination geometry. The N-heterocyclic carbene ligand has an extended S-shaped conformation. The butyl group was refined using a two-part 1:1 disorder model. In the crystal, three unique weak C—H⋯Cl contacts are present. Two of these form a motif described as R 2 1(6) in graph-set notation, while a third forms an R 2 2(8) motif about a crystallographic inversion center. The result is a chain structure which extends parallel to the crystallographic a axis.
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	68
PubMed Central reference number	PMC3274890
Issue Number	Pt 2
Issue Number	pt 2
PubMed reference number	22346837
e-ISSN	16005368
DOI	10.1107/s1600536812000992
Language	English
Publisher	International Union of Crystallography
Publisher Date	2012-01-14
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Nichol et al. 2012
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science