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Tris(4,4'-di-tert-butyl-2,2'-bipyridine-κN,N')molybdenum(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa-oxidohexa-molybdate(VI) acetonitrile tetra-solvate.
| Content Provider | Europe PMC |
|---|---|
| Author | Amarante, Tatiana R. Fernandes, José A. Gonçalves, Isabel S. Almeida Paz, Filipe A. |
| Copyright Year | 2011 |
| Abstract | The asymmetric unit of the title compound, [Mo(C18H24N2)3][Mo6O19]·4CH3CN, comprises an [Mo(di-t-Bu-bipy)3]2+ cation (di-t-Bu-bipy is 4,4′-di-tert-butyl-2,2′-bipyridine), two halves of Lindqvist-type [Mo6O19]2− anions (with each anion completed by the application of a center of inversion) and four acetonitrile solvent molecules. The geometry around the metal atom of the cation resembles a distorted octahedron, with each of the three di-t-Bu-bipy ligands being almost planar [deviation from planarity < 6.3 (2)°]. Supramolecular interactions, namely Mo=O⋯π, C N⋯π, C—H⋯O and C—H⋯N, along with electrostatic forces, mediate the crystal packing. Two of the tert-butyl groups are affected by rotational disorder which was modeled over two distinct positions with major site occupancies of 0.707 (9) and 0.769 (8). |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 67 |
| PubMed Central reference number | PMC3238728 |
| Issue Number | Pt 12 |
| Issue Number | pt 12 |
| PubMed reference number | 22199605 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536811049385 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2011-11-25 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Amarante et al. 2011 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
