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Bis(μ-2-phenyl-acetato-κO:O)bis-[(2,2'-bipyridyl-κN,N')(2-phenyl-acetato-κO)copper(II)] dihydrate.
| Content Provider | Europe PMC |
|---|---|
| Author | Xu, Wei Jin, Ling Liu, Bin-Bin |
| Copyright Year | 2011 |
| Abstract | The molecule of the binuclear title complex, [Cu2(C8H7O2)4(C10H8N2)2]·2H2O, is located on an inversion centre. The Cu atoms are bridged by two O atoms of the monodentate phenylacetate groups [Cu—O = 1.9808 (14) and 2.3668 (14) Å]. The longer of the two bridging Cu—O bonds takes the apical position of the distorted square-pyramidal environment of the Cu atom, which is completed by two N atoms of the chelate 2,2′-bipyridine ligand [Cu—N = 2.0107 (17) and 2.0234 (16) Å]. The molecules are assembled into stacks along [100] through π–π interactions with interplanar distances of 3.630 (4) and 3.407 (3) Å; the resulting stacks are further connected into a three-dimensional supramolecular architecture by O—H⋯O and C—H⋯O hydrogen-bonding interactions. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 67 |
| PubMed Central reference number | PMC3201355 |
| Issue Number | Pt 10 |
| Issue Number | pt 10 |
| PubMed reference number | 22058686 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536811035483 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2011-09-14 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Xu et al. 2011 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
