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catena-Poly[[[diaqua-cobalt(II)]-μ-(3,5-dinitro-2-oxidobenzoato)-κO,O:O-[tetra-aqua-cobalt(II)]-μ-(3,5-dinitro-2-oxidobenzoato)-κO:O,O] dihydrate].
| Content Provider | Europe PMC |
|---|---|
| Author | Smith, Graham Wermuth, Urs D. |
| Copyright Year | 2011 |
| Abstract | In polymeric title compound, {[Co2(C7H2N2O7)2(H2O)6]·2H2O}n, obtained from the reaction of 3,5-dinitrosalicylic acid with cobalt(II) acetate, both CoII atoms are located on inversion centres and exhibit a distorted octahedral coordination geometry. The coordination sphere about one CoII atom comprises four O-atom donors from two bidentate chelate (Ophenolate and Ocarboxyl) and bridging dianionic ligands and two water molecules [Co—O range = 2.0249 (11)–2.1386 (14) Å], while that about the second CoII atom has four water molecules and two bridging carboxylate O-donor atoms [Co—O range = 2.0690 (14)–2.1364 (11) Å]. The coordinated water molecules as well as the water molecules of solvation give O—H⋯O water–water and water–carboxyl hydrogen-bonding interactions in the three-dimensional framework structure. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 67 |
| PubMed Central reference number | PMC3050395 |
| Issue Number | Pt 1 |
| Issue Number | pt 1 |
| PubMed reference number | 21522530 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536810052694 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2010-12-24 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Smith and Wermuth 2011 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
