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Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| Content Provider | Europe PMC |
|---|---|
| Author | Xian, Hua Duan, Hai-Bao |
| Copyright Year | 2011 |
| Abstract | In the ionic title complex, (C13H11N2)2[Ni(C4N2S2)2], the NiII ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)2]2− dianion (mnt2− is maleonitriledithiolate) and one 1-(3-cyanobenzyl)pyridinium cation ([CNBzPy]+). The NiII ion in the [Ni(mnt)2]2− anion is coordinated by four S atoms of two mnt2− ligands, and exhibits square-planar coordination geometry. In the [CNBzPy]+ cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methylene C atom that links them. The crystal structure is stabilized by Coulombic interactions. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 67 |
| PubMed Central reference number | PMC3050285 |
| Issue Number | Pt 1 |
| Issue Number | pt 1 |
| PubMed reference number | 21522588 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536810051263 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2010-12-11 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Xian and Duan 2011 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
