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(μ-Oxalato-κO,O:O,O)bis-[bis-(2,2'-bipyridine-κN,N')cobalt(II)] μ(6)-oxido-dodeca-μ(2)-oxido-hexa-oxido-hexa-tungstate(VI).
| Content Provider | Europe PMC |
|---|---|
| Author | Shi, Congwen Fan, Liming Wei, Peihai Li, Bin Zhang, Xiutang |
| Copyright Year | 2010 |
| Abstract | The asymmetric unit of the title compound, [Co2(C2O4)(C10H8N2)4][W6O19], consists of one half of the complex [Co2(C2O4)(C10H8N2)4]2+ cation and one half of the Lindqvist-type [W6O19]2− isopolyanion. Both constituents are completed by crystallographic inversion symmetry. In the dimeric cation, the CoII atom is surrounded in a distorted octahedral coordination by four N atoms from two chelating 2,2′-bipyridine ligands and by two O atoms from the chelating oxalate anion. The Lindqvist-type anion exhibits the characteristic W—O bond-length distribution, with the shortest bonds being the W—Oterminal bonds and the longest being those to the central O atom. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 66 |
| PubMed Central reference number | PMC3006761 |
| Issue Number | Pt 7 |
| Issue Number | pt 7 |
| PubMed reference number | 21587738 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536810023007 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2010-06-18 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Shi et al. 2010 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
