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1,12-Bis(2-carboxy-phen-yl)-5,8-dioxa-2,11-diaza-dodecane-2,11-diium dichloride methanol solvate.
| Content Provider | Europe PMC |
|---|---|
| Author | Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. |
| Copyright Year | 2010 |
| Abstract | In the title salt hydrate, C22H30N2O6 2+·2Cl−·CH4O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl−, N+—H⋯Cl− and N+—H⋯O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C—H⋯O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H⋯π contacts. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 66 |
| PubMed Central reference number | PMC2980219 |
| Issue Number | Pt 1 |
| Issue Number | pt 1 |
| PubMed reference number | 21580166 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536809051824 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2009-12-04 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Johnson et al. 2010 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
