NDLI: cis,trans,cis,cis-7-tert-Butyl-dimethyl-silyl-oxy-4,10-dimethyl-tetra-cyclo[5.4.1.0.0]dodecan-2-one.

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cis,trans,cis,cis-7-tert-Butyl-dimethyl-silyl-oxy-4,10-dimethyl-tetra-cyclo[5.4.1.0.0]dodecan-2-one.

Content Provider	Europe PMC
Author	Weyermann, Philipp Keese, Reinhart Stoeckli-Evans, Helen
Copyright Year	2010
Abstract	In the structure of the title compound, C20H34O2Si, a cis,trans,cis,cis-[4.5.5.5]fenestrane derivative, the geometry of the central C(C)4 substructure shows considerable distortion from an ideal tetrahedral arrangement towards planarity, with two opposite bridgehead bond angles of 128.87 (18) and 122.83 (17)°. The other bridgehead angle of the trans-bicyclo[3.3.0]octane subunit is also large [126.57 (19)°].
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	66
PubMed Central reference number	PMC2979968
Issue Number	Pt 2
Issue Number	pt 2
PubMed reference number	21579769
e-ISSN	16005368
DOI	10.1107/s1600536810000887
Language	English
Publisher	International Union of Crystallography
Publisher Date	2010-01-13
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Weyermann et al. 2010
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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