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Benzene-1,3,5-triyl tris-(2,2-dimethyl-propanoate).
| Content Provider | Europe PMC |
|---|---|
| Author | Haines, Alan H. Hughes, David L. |
| Copyright Year | 2009 |
| Abstract | In the title compound, C21H30O6, the three acetoxy groups are essentially planar with their normals rotated by −57.75 (4), −62.36 (4) and 63.36 (4)° from the normal to the mean plane of the C6 ring. The arrangement of carbonyl groups around the ring is of two groups ‘up’ and one ‘down’, and the propeller-style arrangement of substituent groups is spoiled with the plane of the ‘down’ group twisted in the opposite direction; all the Cring—O—C—CMe3 conformations are trans. In the crystal, aromatic π–π stacking occurs [centroid–centroid separation = 3.320 (1) Å]; the other main intermolecular interaction is a C—H⋯π-ring contact on the opposing side from the overlapped ring pairing; there are no short C—H⋯O contacts. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 65 |
| PubMed Central reference number | PMC2971883 |
| Issue Number | Pt 12 |
| Issue Number | pt 12 |
| PubMed reference number | 21578973 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536809050028 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2009-11-28 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Haines and Hughes 2009 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
