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Bis(triethyl-ammonium) bis-(μ-pyrazine-2,3-dithiol-ato)bis-(pyrazine-2,3-dithio-lato)diferrate(III) methanol disolvate.
| Content Provider | Europe PMC |
|---|---|
| Author | Yamaguchi, Toshiki Masaoka, Shigeyuki Sakai, Ken |
| Copyright Year | 2009 |
| Abstract | In the title compound, (C6H16N)2[Fe2(C4H2N2S2)4]·2CH4O, the [FeIII(pdt)2]− anion (pdt is pyrazine-2,3-dithiolate) forms a centrosymmetric dimer supported by two FeIII—S bonds [Fe—S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b axis via π–π stacking interactions, the interplanar separation between adjacent dimers being 3.51 (2) Å. The methanol solvent molecule is involved in two hydrogen bonds in which the hydroxyl group acts as a hydrogen-bond donor to the N atom of a pdt ligand and the O atom acts as an acceptor for the NH group of the triethylammonium cation. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 65 |
| PubMed Central reference number | PMC2967914 |
| Issue Number | Pt 1 |
| Issue Number | pt 1 |
| PubMed reference number | 21581543 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536808041949 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2008-12-17 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Yamaguchi et al. 2009 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
