NDLI: catena-Poly[[tetra-kis(μ(2)-acetato-κO:O')dicopper(II)(Cu-Cu)]-μ(2)-acetato-κO:O'-[bis-[μ(2)-3-(dimethyl-amino)propan-1-olato]-κN,O:O;κO:N,O-bis-[(tetra-hydro-furan-κO)copper(II)]]-μ(2)-acetato-κO:O'].

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catena-Poly[[tetra-kis(μ(2)-acetato-κO:O')dicopper(II)(Cu-Cu)]-μ(2)-acetato-κO:O'-[bis-[μ(2)-3-(dimethyl-amino)propan-1-olato]-κN,O:O;κO:N,O-bis-[(tetra-hydro-furan-κO)copper(II)]]-μ(2)-acetato-κO:O'].

Content Provider	Europe PMC
Author	Shahid, Muhammad Mazhar, Muhammad Helliwell, Madeleine Akhtar, Javeed Ahmad, Kibriya
Copyright Year	2008
Abstract	The title complex, [Cu4(C5H12NO)2(C2H3O2)6(C4H8O)2]n, consists of dinuclear [Cu2(C5H12NO)2(THF)2] (THF is tetrahydrofuran) and [Cu2(CH3COO)4] units linked through acetate ions, generating parallel one-dimensional polymeric chains propagating in the [10] direction. In the first dinuclear unit, CuII ions related by inversion symmetry are bridged by two 3-(dimethylamino)propan-1-olate ligands. Likewise, a pair of inversion-related CuII ions are bridged by four acetate groups. The crystallographically independent Cu centers are linked to one another by a single bridging acetate group, generating an infinite chain. The distorted square-pyramidal coordination of the first metal center is completed with an apical THF molecule, with a long Cu—O bond length of 2.476 (5) Å. The geometry around the other metal atom is close to octahedral, and the Cu⋯Cu separation in this unit is 2.652 (1) Å. The distance between the metal centers in the first dinuclear unit is considerably longer [3.068 (1) Å], suggesting little or no bonding interaction. The Cu⋯Cu separation between two acetate-bridged independent Cu centers is 4.860 (2) Å. The THF molecule has methylene groups disordered over two positions, with occupancies of 0.608 (13) and 0.392 (13).
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	64
PubMed Central reference number	PMC2960524
Issue Number	Pt 9
Issue Number	pt 9
PubMed reference number	21201596
e-ISSN	16005368
DOI	10.1107/s1600536808024148
Language	English
Publisher	International Union of Crystallography
Publisher Date	2008-08-09
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Shahid et al. 2008
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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