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catena-Poly[[[diaqua-cobalt(II)]bis-(μ-1,3-di-4-pyridylpropane-κN:N')] bis-(perchlorate) bis-(1,3-di-4-pyridyl-propane) bis-(2-methyl-4-nitro-aniline)].
| Content Provider | Europe PMC |
|---|---|
| Author | Fu, Zhiyong Chen, Yuan Yi, Jianglong |
| Copyright Year | 2008 |
| Abstract | In the title compound, {[Co(C13H14N2)2(H2O)2](ClO4)2·2C13H14N2·2C7H8N2O2}n, the CoII ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octahedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the CoII ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane molecule, one 2-methyl-4-nitroaniline molecule and one perchlorate anion. In the crystal structure, intermolecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 64 |
| PubMed Central reference number | PMC2960494 |
| Issue Number | Pt 9 |
| Issue Number | pt 9 |
| PubMed reference number | 21201638 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536808026470 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2008-08-23 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Fu et al. 2008 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |