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High performance photocatalyst TiO2@UiO-66 applied to degradation of methyl orange.
| Content Provider | Europe PMC |
|---|---|
| Author | Yang, Jingyi Chang, Xue Wei, Fang Lv, Zixiao Liu, Huiling Li, Zhan Wu, Wangsuo Qian, Lijuan |
| Abstract | MOFs have considerable adsorption capacity due to their huge specific surface area. They have the characteristics of photocatalysts for their organic ligands can absorb photons and produce electrons. In this paper, the photodegradation properties of TiO2 composites loaded with UiO-66 were investigated for the first time for MO. A series of TiO2@UiO-66 composites with different contents of TiO2 were prepared by a solvothermal method. The photocatalytic degradation of methyl orange (MO) was performed using a high-pressure mercury lamp as the UV light source. The effects of TiO2 loading, catalyst dosage, pH value, and MO concentration were investigated. The results showed that the degradation of MO by TiO2@UiO-66 could reach 97.59% with the addition of only a small amount of TiO2 (5 wt%). TiO2@UiO-66 exhibited significantly enhanced photoelectron transfer capability and inhibited efficient electron–hole recombination compared to pure TiO2 in MO degradation. The composite catalyst indicated good stability and reusability when they were recycled three times, and the photocatalytic reaction efficiencies were 92.54%, 88.76%, and 86.90%. The results provide a new option to design stable, high-efficiency MOF-based photocatalysts. Supplementary Information The online version contains supplementary material available at 10.1186/s11671-023-03894-6. |
| Related Links | https://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC10495301&blobtype=pdf |
| Volume Number | 18 |
| DOI | 10.1186/s11671-023-03894-6 |
| PubMed Central reference number | PMC10495301 |
| Issue Number | 1 |
| PubMed reference number | 37695406 |
| Journal | Discover Nano [Discov Nano] |
| e-ISSN | 27319229 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2023-09-11 |
| Publisher Place | New York |
| Access Restriction | Open |
| Rights License | Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. © The Author(s) 2023 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Condensed Matter Physics Materials Science |