NDLI: Electrochemically Driven Hydrogen Atom Transfer Catalysis: A Tool for C(sp<sup>3</sup>)/Si-H Functionalization and Hydrofunctionalization of Alkenes.

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Electrochemically Driven Hydrogen Atom Transfer Catalysis: A Tool for C(sp³)/Si-H Functionalization and Hydrofunctionalization of Alkenes.

Content Provider	Europe PMC
Author	Zhang, Sheng Findlater, Michael
Copyright Year	2023
Abstract	Electrochemically driven hydrogen atom transfer (HAT)catalysisprovides a complementary approach for the transformation of redox-inactivesubstrates that would be inaccessible to conventional electron transfer(ET) catalysis. Moreover, electrochemically driven HAT catalysis couldpromote organic transformations with either hydrogen atom abstractionor donation as the key step. It provides a versatile and effectivetool for the direct functionalization of C(sp3)–H/Si–Hbonds and the hydrofunctionalization of alkenes. Despite these attractiveproperties, electrochemically driven HAT catalysis has been largelyoverlooked due to the lack of understanding of both the catalyticmechanism and how catalyst selection should occur. In this Review,we give an overview of the HAT catalysis applications in the directC(sp3)–H/Si–H functionalization and hydrofunctionalizationof alkenes. The mechanistic pathways, physical properties of the HATmediators, and state-of-the-art examples are described and discussed.
Related Links	https://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC10334887&blobtype=pdf
Journal	ACS Catalysis [ACS Catal]
Volume Number	13
DOI	10.1021/acscatal.3c01221
PubMed Central reference number	PMC10334887
Issue Number	13
PubMed reference number	37441236
e-ISSN	21555435
Language	English
Publisher	American Chemical Society
Publisher Date	2023-06-16
Access Restriction	Open
Rights License	Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). © 2023 The Authors. Published by American Chemical Society
Subject Keyword	hydrogen atom transfer catalysis electrochemical transformation C(sp3)−H functionalization hydrofunctionalizationof alkenes
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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Electrochemically Driven Hydrogen Atom Transfer Catalysis: A Tool for C(sp3)/Si-H Functionalization and Hydrofunctionalization of Alkenes.

Electrochemically Driven Hydrogen Atom Transfer Catalysis: A Tool for C(sp³)/Si-H Functionalization and Hydrofunctionalization of Alkenes.