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| Content Provider | EDP Sciences |
|---|---|
| Author | F. G. Shi K. Okuyama |
| Abstract | A model for the temperature dependence of electrical conduction in a porous silicon (PS) layer is introduced based on the consideration that the onset of electrical conduction is dependent on the formation of a continuous network of conducting sites extending the entire thickness of a PS layer. At an arbitrary temperature, a PS layer consists of both unblocked and blocked sites (blocking energies are larger than thermal fluctuation energy). The fraction of unblocked sites increases with temperature. At low temperatures () a PS layer is mainly dominated by a continuous network of blocked sites, while discrete unblocked sites do not form any continuous network extending the entire thickness of a PS layer. At medium temperatures () both continuous networks of unblocked and blocked sites appear in a PS layer. And at higher temperatures (), a PS layer is mainly dominated by a continuous network of unblocked sites, while discrete blocked sites do not form any continuous network extending the entire thickness of a PS layer. Contrary to the prevalent views, the overall temperature dependence of the electrical conductivity of a PS is not always Arrhenius: it obeys a Vogel-Tammann-Fulcher (VTF) law at , becomes insulating at , and exhibits the Arrhenius behavior only for . Both T1 and T2 are found to increase with the decrease silicon nanocrytallites sizes. The VTF behavior was derived using the mean-field approximation for Ising model and found to agree with experimental evidences. |
| Ending Page | 240 |
| Starting Page | 234 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 02955075 |
| Alternate Webpage(s) | https://epljournal.edpsciences.org/articles/epl/abs/2001/08/6499/6499.html |
| e-ISSN | 12864854 |
| Issue Number | 2 |
| Journal | Europhysics Letters |
| Volume Number | 54 |
| DOI | 10.1209/epl/i2001-00300-9 |
| Language | English |
| Publisher | EDP Sciences |
| Publisher Date | 2001-04-01 |
| Access Restriction | One Nation One Subscription (ONOS) |
| Rights Holder | © EDP Sciences, 2001 |
| Subject Keyword | Electronic transport in mesoscopic systems Electronic transport phenomena in thin films Nanocrystalline materials |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy |
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