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Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
| Content Provider | Directory of Open Access Journals (DOAJ) |
|---|---|
| Author | Scott R. Patrick Sebastien Meiries Alba Collado Danila Gasperini Steven P. Nolan |
| Abstract | Three new Au(I) complexes of the formula [Au(NHC)(NTf2)] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the 'ITent' ('Tent' for 'tentacular') family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated. |
| Related Links | https://doi.org/10.3762/bjoc.11.196 |
| e-ISSN | 18605397 |
| DOI | 10.3762/bjoc.11.196 |
| Journal | Beilstein Journal of Organic Chemistry |
| Issue Number | 1 |
| Volume Number | 11 |
| Language | English |
| Publisher | Beilstein-Institut |
| Publisher Date | 2015-01-01 |
| Publisher Place | Germany |
| Access Restriction | Open |
| Subject Keyword | Science Organic Chemistry Catalysis Flexible and Bulky Ligands Gold Ligand Design N-heterocyclic Carbenes |
| Content Type | Text |
| Resource Type | Article |