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Structural tuning of Montmorillonite clays by pillaring: Designing of shape selective solid acid catalysts and PANI - Montmorillonite nanocomposites
| Content Provider | CUSAT-Thesis |
|---|---|
| Advisor | Dr.Sugunan, S |
| Researcher | Binitha, N N |
| Abstract | Green chemistry boots eco-friendly,natural clays as catalysts in the chemical as well as in the pharmaceutical industry.Industry demands thermal stability,mechanical strength etc for the catalyst and there the modification methods becomes important.Pillaring tunes clays as efficient catalytic templates for shape selective organic synthesis.Here pillared clays are used as promising alternatives for the environmentally hazardous homogeneous catalysts in some industrially important Friedel-Crafts alkylation reactions of arenes with lower alchohols and higher olefins.The layer structure is enhanced upon pillaring and allows the nanocomposite formation with polyaniline to develop today’s nanoscale diameter devices.Present work gives an entry of pillared clays to the world of conducting composite nanofibers. |
| File Format | |
| Language | English |
| Publisher Institution | Cochin University of Science and Technology |
| Access Restriction | Open |
| Subject Keyword | Clays Montmorillonite Clays Pillaring Ethylbenzene Ethanol Benzene PANI - montmorillonite nanocomposites Alkylation Cumene Nanocomposites Green chemistry Applied Chemistry |
| Content Type | Text |
| Educational Degree | Doctor of Philosophy (Ph.D.) |
| Resource Type | Thesis |