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| Content Provider | CSIR - National Institute of Science Communication and Policy Research (NISCPR) |
|---|---|
| Author | Nadar, P. Ananthakrishna Rajarathinam, D. |
| Abstract | A series of 4- substituted 1-naphthyl acetates have been prepared. The kinetics of their ammonolysis have been followed at 20°, 25° and 30°C under pseudo-first order conditions at different pH in water containing 1% dioxan at an ionic strength of 1.0 mol dm-3. The possible mechanisms suggest the existence of general base catalysis for 4-methyl-1-naphthyl acetate. For esters with electron-withdrawing substituents, ammonolysis proceeds through an unassisted simple nucleophilic substitution pathway. The alkaline hydrolysis of all the esters is also followed under identical reaction conditions. |
| Ending Page | 753 |
| Starting Page | 749 |
| ISSN | 03764710 |
| e-ISSN | 09750975 |
| Journal | Indian Journal of Chemistry -Section A (IJC-A) |
| Issue Number | 09 |
| Volume Number | 36A |
| Language | English |
| Publisher | CSIR-NISCAIR, India |
| Publisher Date | 1997-09-01 |
| Access Restriction | Open |
| Rights License | CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| Subject Keyword | Research Journal Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Inorganic Chemistry Physical and Theoretical Chemistry |
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