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Applications of time-resolved synchrotron X-ray diffraction to cation exchange, crystal growth and biomineralization reactions
| Content Provider | CiteSeerX |
|---|---|
| Author | Heaney, P. J. Post, J. E. Fischer, T. B. Hummer, D. R. Lopano, C. L. Wall, A. J. |
| Abstract | Advances in the design of environmental reaction cells and in the collection of X-ray diffraction data are transforming our ability to study mineral-fluid interactions. The resulting increase in time resolution now allows for the determination of rate laws for mineral reactions that are coupled to atomic-scale changes in crystal structure. Here we address the extension of time-resolved synchrotron diffraction techniques to four areas of critical importance to the cycling of metals in soils: (1) cation exchange; (2) biomineralization; (3) stable isotope fractionation during redox reactions; and (4) nucleation and growth of nanoscale oxyhydroxides. |
| File Format | |
| Access Restriction | Open |
| Content Type | Text |