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Combustion and flame 85:185-194 (1991) 185 comparison between shock initiations of detonation using thermally-sensitive and chain-branching chemical models.
| Content Provider | CiteSeerX |
|---|---|
| Author | Dold, J. W. Kapila, A. K. |
| Abstract | This article shows that, unlike the situation in many other combustion problems, the progress towards detonation behind an initiating shock wave when the chemistry is modeled using a radical chain-branching mechanism is fundamentally different from the progress found when a global one-step model is used. In the latter case, a uniformly supersonic (shockless) wave of chemical activity is found to emerge at the end of an induction process. Only after this "induction flame " slows down significantly is it possible for a genuine propagation mechanism to create a Zeldovich-von Neumann-DSring detonation structure. When dominated by chain branching, the reaction wave produced by the induction process is subsonic, and can therefore be influenced by propagating thermodynamic disturbances (as originally pointed out by Strehlow). The resulting chemical-hydrodynamic interaction causes an acceleration of the wave prior to the emergence of the detonation. It is suggested that the existence of these two distinct forms of initiation may provide a means of testing for the relative importance of possible chain-branching and state-sensitive mechanisms in the initiation of detonations, especially where little kinetic data are yet available (as, for example, in condensed explosives). |
| File Format | |
| Access Restriction | Open |
| Subject Keyword | Combustion Flame Detonation Using Chain-branching Chemical Model Comparison Shock Initiation Induction Process Zeldovich-von Neumann-dsring Detonation Structure Global One-step Model Little Kinetic Data Radical Chain-branching Mechanism Chemical-hydrodynamic Interaction Reaction Wave Many Combustion Problem Chemical Activity Shock Wave Latter Case Thermodynamic Disturbance Uniformly Supersonic Relative Importance Genuine Propagation Mechanism Condensed Explosive State-sensitive Mechanism Chain Branching Induction Flame |
| Content Type | Text |
| Resource Type | Article |