NDLI: Pulsed-high field/high-frequency epr spectroscopy.

Please wait, while we are loading the content...

Pulsed-high field/high-frequency epr spectroscopy.

Content Provider	CiteSeerX
Author	Fuhs, Michael
Abstract	Abstract. Pulsed high-field/high-frequency electron paramagnetic resonance (EPR) spectroscopy is used to disentangle many kinds of different effects often obscured in con-tinuous wave (cw) EPR spectra at lower magnetic fields/microwave frequencies. While the high magnetic field increases the resolution of G tensors and of nuclear Larmor fre-quencies, the high frequencies allow for higher time resolution for molecular dynamics as well as for transient paramagnetic intermediates studied with time-resolved EPR. Pulsed EPR methods are used for example for relaxation-time studies, and pulsed Electron Nuclear DOuble Resonance (ENDOR) is used to resolve unresolved hyperfine structure hidden in inhomogeneous linewidths. In the present article we introduce the basic concepts and selected applications to structure and mobility studies on electron transfer systems, reaction centers of photosynthesis as well as biomimetic models. The article concludes with an introduction to stochastic EPR which makes use of another concept for investigating resonance systems in order to increase the excitation band-width of pulsed EPR. The limited excitation bandwidth of pulses at high frequency is one of the main limitations which, so far, made Fourier transform methods hardly feasible. 1
File Format	PDF
Access Restriction	Open
Subject Keyword	Pulsed-high Field High-frequency Epr Spectroscopy High Frequency Inhomogeneous Linewidths Time Resolution Unresolved Hyperfine Structure Basic Concept Time-resolved Epr Present Article Epr Spectrum Mobility Study Pulsed Epr Different Effect High-field High-frequency Electron Paramagnetic Resonance High Magnetic Field Biomimetic Model Stochastic Epr Electron Nuclear Double Resonance Relaxation-time Study Epr Method Nuclear Larmor Fre-quencies Molecular Dynamic Con-tinuous Wave Many Kind Resonance System Magnetic Field Limited Excitation Bandwidth Excitation Band-width Electron Transfer System Transient Paramagnetic Intermediate Main Limitation Reaction Center
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in