NDLI: Performance of Thermal Enhancement Materials in High Pressure Metal Hydride Storage Systems

Content Provider	The American Society of Mechanical Engineers (ASME) Digital Collection
Author	Pourpoint, Timothe´e L. Sisto, Aaron Kyle, C. Smith Tyler, G. Voskuilen Milan, K. Visaria Zheng, Yuan Timothy, S. Fisher
Copyright Year	2008
Abstract	Over the past two years, key issues associated with the development of realistic metal hydride storage systems have been identified and studied at Purdue University’s Hydrogen Systems Laboratory, part of the Energy Center at Discovery Park. Ongoing research projects are aimed at the demonstration of a prototype large-scale metal hydride tank that achieves fill and release rates compatible with current automotive use. The large-scale storage system is a prototype with multiple pressure vessels compatible with 350 bar operation. Tests are conducted at the Hydrogen Systems Lab in a 1000 ft2 laboratory space comprised of two test cells and a control room that has been upgraded for hydrogen service compatibility. The infrastructure and associated data acquisition and control systems allow for remote testing with several kilograms of high-pressure reversible metal hydride powder. Managing the large amount of heat generated during hydrogen loading directly affects the refueling time. However, the thermal management of hydride systems is problematic because of the low thermal conductivity of the metal hydrides (∼ 1 W/m-K). Current efforts are aimed at optimizing the filling-dependent thermal performance of the metal hydride storage system to minimize the refueling time of a practical system. Combined heat conduction within the metal hydride and the enhancing material particles, across the contacts of particles and within the hydrogen gas between non-contacted particles plays a critical role in dissipating heat to sustain high reaction rates during refueling. Methods to increase the effective thermal conductivity of metal hydride powders include using additives with substantially higher thermal conductivity such as aluminum, graphite, metal foams and carbon nanotubes. This paper presents the results of experimental studies in which various thermal enhancement materials are added to the metal hydride powder in an effort to maximize the effective thermal conductivity of the test bed. The size, aspect ratio, and intrinsic thermal conductivity of the enhancement materials are taken into account to adapt heat conduction models through composite nanoporous media. Thermal conductivity and density of the composite materials are measured and enhancement metrics are calculated to rate performance of composites. Experimental results of the hydriding process of thermally enhanced metal hydride powder are compared to un-enhanced metal hydride powder and to model predictions. The development of the Hydrogen Systems Laboratory is also discussed in light of the lessons learned in managing large quantities of metal hydride and high pressure hydrogen gas.
Sponsorship	Heat Transfer Division
Starting Page	37
Ending Page	46
Page Count	10
File Format	PDF
ISBN	9780791848470
DOI	10.1115/HT2008-56450
e-ISBN	0791838323
Volume Number	Heat Transfer: Volume 1
Conference Proceedings	ASME 2008 Heat Transfer Summer Conference collocated with the Fluids Engineering, Energy Sustainability, and 3rd Energy Nanotechnology Conferences
Language	English
Publisher Date	2008-08-10
Publisher Place	Jacksonville, Florida, USA
Access Restriction	Subscribed
Subject Keyword	Metal foams Hydrogen Aluminum Control rooms Data acquisition Metals Carbon nanotubes Control systems Density Heat conduction High pressure (physics) Heat Storage Composite materials Pressure vessels Particulate matter Chemical kinetics Graphite Thermal conductivity Thermal management Engineering prototypes Testing
Content Type	Text
Resource Type	Article

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